Emission Anisotropy of Fluorescence of Polar Molecules
نویسنده
چکیده
The emission anisotropy (EA) of 4-Dimethyl-amino-4'nitrostilbene (DNS), 4-Amino-4'-nitrostilbene (ANS) and 2,5-Di(4-biphenylyl)oxazole (BBO) was observed to be decreasing with increasing dielectric constant e of the solvent. The effect is interpreted as an influence of the Onsager reaction field on the volume of the solvent shell, which in the excited state is smaller in solvents with larger e. This favors the depolarisation by the irrregular Brow nian rotation.
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